Intercalation of <i>n</i>-alkylamines and alkylene diamines into carboxyl functionalized lamellar-type silsesquioxane
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- OHSHITA Hironori
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
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- ITO Machi
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
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- IDOTA Naokazu
- Kagami Memorial Research Institute for Materials Science and Technology, Waseda University
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- MEHDI Ahmad
- Institut Charles Gerhardt, Chimie Moléculaire et Organisation du Solide, Université de Montpellier
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- BOURY Bruno
- Institut Charles Gerhardt, Chimie Moléculaire et Organisation du Solide, Université de Montpellier
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- SUGAHARA Yoshiyuki
- Department of Applied Chemistry, School of Science and Engineering, Waseda University Kagami Memorial Research Institute for Materials Science and Technology, Waseda University
抄録
A sol–gel-derived carboxyl-functionalized lamellar-type silsesquioxane was prepared to investigate its potential for use as a host material for intercalation reactions with n-alkylamines and alkylene diamines. Upon intercalation of n-alkylamines and alkylene diamines, the interlayer distances increased as shown by X-ray powder diffraction patterns, and IR spectra showed the presence of absorption bands attributable to ν(COO−) and δ(NH3+) modes. The amounts of intercalated n-alkylamines were determined from n-CnH2n+1NH2/–COOH molar ratios which, based on CHN analysis, exhibited values from 0.76 to 0.88; whereas the values determined for the alkylene diamines were 0.83 (NH2C4H8NH2), 0.45 (NH2C8H16NH2) and 0.33 (NH2C12H24NH2). These results show that intercalation of n-alkylamines and alkylene diamines into lamellar-type silsesquioxane bearing carboxyl groups proceeded successfully via acid-base mechanisms.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 124 (10), 1090-1093, 2016
公益社団法人 日本セラミックス協会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282680263534208
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- NII論文ID
- 130005605991
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- ISSN
- 13486535
- 18820743
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可