Reaction Kinetics on Allophane–Titania Nanocomposite Electrodes for Photofuel Cells

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  • Nishikiori Hiromasa
    Department of Materials Chemistry, Faculty of Engineering, Shinshu University
  • Furuichi Naoyuki
    Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University
  • Teshima Katsuya
    Department of Materials Chemistry, Faculty of Engineering, Shinshu University
  • Yamashita Hiromi
    Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University

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Other Title
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Abstract

<p>The reaction process on allophane-dispersing titania electrodes of photofuel cells was investigated in electrolytes containing glucose as the fuel material at different concentrations. A low allophane amount improved the glucose adsorption–degradation relay on the electrodes. The dispersion process of the glucose molecules adsorbed on the allophane to the titania was the rate-determining step in the present systems. The reaction rate decreased when high amounts of intermediate products were adsorbed on the allophane and titania surface.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 46 (5), 659-661, 2017

    The Chemical Society of Japan

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