Specific Enhancement of Activity of Carbon-supported Single-site Co Catalyst in the Microwave-assisted Solvent-free Aerobic Oxidation

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Author(s)

    • Yoshii Takeharu
    • Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University
    • Nakatsuka Kazuki
    • Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University
    • Kuwahara Yasutaka
    • Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University|Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University
    • Mori Kohsuke
    • Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University|Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University|JST, PRESTO
    • Yamashita Hiromi
    • Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University|Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University

Abstract

<p>The structure–activity relationship of carbon-supported Co catalysts was investigated in solvent-free aerobic oxidation of ethylbenzene under microwave irradiation. A single-site Co species show specifically high catalytic activity under microwave irradiation compared to conventional heating, while the oxidation is not accelerated by microwave when Co nanoparticle catalysts are used.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 46(6), 789-791, 2017

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130005689359
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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