Viologens for Coenzymes of Biocatalysts with the Function of CO₂ Reduction and Utilization

• Amao Yutaka

  The Advanced Research Institute for Natural Science and Technology, Osaka City University Graduate School of Science, Osaka City University Research Centre for Artificial Photosynthesis (ReCAP), Osaka City University

Bibliographic Information

Other Title

• Viologens for coenzymes of biocatalysts with the function of CO2 reduction and utilization

Abstract

In this review, the recent studies on 1) the visible-light-induced reduction of CO₂ to formic acid catalyzed by formate dehydrogenase (FDH) via the reduction of a 4,4′- or 2,2′-bipyridinium salt (BP²⁺) by a photosensitizer, 2) the electrochemical properties of BP²⁺, and 3) the enzymatic kinetic properties of the interaction between the reduced forms of BP²⁺ and FDH are reviewed. Moreover, visible-light-induced biocatalytic C–C bond formation using CO₂ as a feedstock via photoreduction of the phenylviologen derivative is introduced.

Journal

• Chemistry Letters

  Chemistry Letters 46 (6), 780-788, 2017

  The Chemical Society of Japan

Keywords

• Photoredox system
• CO₂ fixation
• Coenzyme of biocatalyst

Details

• CRID: 1390001204589527040
• NII Article ID: 130005689376
• DOI: 10.1246/cl.161189
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://www.journal.csj.jp/doi/pdf/10.1246/cl.161189
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed