Hydrothermal Synthesis of Ce-doped BaZrO<sub>3</sub> Fine Particles and Their Three-way Catalytic Performance for Exhaust Gas Purification

  • SEINO Yuki
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • KANIE Kiyoshi
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
  • MURAMATSU Atsushi
    Institute of Multidisciplinary Research for Advanced Materials, Tohoku University

Bibliographic Information

Other Title
  • セリウムドープジルコン酸バリウム微粒子の水熱合成と三元触媒担体としての排ガス浄化特性評価
  • セリウムドープジルコンサン バリウム ビリュウシ ノ スイネツ ゴウセイ ト サンゲン ショクバイタンタイ ト シテ ノ ハイガス ジョウカ トクセイ ヒョウカ

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Abstract

<p>Cerium-doped barium zirconate (Ce-doped BaZrO3) fine particles with high crystallinity was prepared by a hydrothermal reaction using barium hydroxide, CeCl3, and a Zr-triethanolamine complex. Characterization of the Ce-doped BaZrO3 particles revealed that utilization of the water-stable Zr-triethanolamine complex was an efficient way to introduce cerium ions into the BaZrO3 perovskite crystal structure. The three-way catalytic activity of the Ce-doped BaZrO3 for an exhaust gas conversion reaction was investigated under a stoichiometric condition (CO 0.5%, C3H6 400 ppm, NO 500 ppm, O2 0.49%, H2 0.17%, CO2 14%, H2O 10% in N2). The Ce-doped BaZrO3 exhibited a remarkable low temperature NOx cleaning performance when the Ce-doped BaZrO3 was applied as an alternative for an Al2O3 support.</p>

Journal

  • Journal of MMIJ

    Journal of MMIJ 133 (6), 116-122, 2017

    The Mining and Materials Processing Institute of Japan

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