Aliphatic Glucoside, Zanthoionic Acid and Megastigmane Glucosides : Zanthoionosides A-E from the Leaves of Zanthoxylum ailanthoides

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  • Teshima Serika
    Graduate School of Biomedical and Health Sciences, Hiroshima University
  • Kawakami Susumu
    Faculty of Pharmacy, Yasuda Women’s University
  • Sugimoto Sachiko
    Graduate School of Biomedical and Health Sciences, Hiroshima University
  • Matsunami Katsuyoshi
    Graduate School of Biomedical and Health Sciences, Hiroshima University
  • Otsuka Hideaki
    Graduate School of Biomedical and Health Sciences, Hiroshima University Faculty of Pharmacy, Yasuda Women’s University
  • Shinzato Takakazu
    Subtropical Field Science Center, Faculty of Agriculture, University of the Ryukyus

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  • Aliphatic Glucoside, Zanthoionic Acid and Megastigmane Glucosides: Zanthoionosides A–E from the Leaves of <i>Zanthoxylum ailanthoides</i>

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<p>From the leaves of Zanthoxylum ailanthoides, 4′-O-p-E-coumaric acid esters of 2-propanol β-D-glucopyranoside, megastigmane and megastigmane glucosides were isolated. Their structures were elucidated by spectroscopic evidence. The absolute configurations of the megastigmane and aglycone of megastigmane glucosides were determined by the octant rule and modified Mosher’s method after protection of carboxylic acids by p-bromophenacyl esters and primary alcohols by pivaloyl esters.</p>

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