Formation of Dibenzopentalene-linking Polymers under the Two-zone CVD and Wet Conditions

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Author(s)

    • Saito Masaichi
    • Department of Chemistry, Graduate School of Science and Engineering, Saitama University
    • Suda Yuki
    • Department of Chemistry, Graduate School of Science and Engineering, Saitama University
    • Furukawa Shunsuke
    • Department of Chemistry, Graduate School of Science and Engineering, Saitama University

Abstract

<p>Introduction of pentagonal units into carbon-based materials is of considerable interest to perturb the geometric and electronic properties of the original structures composed of only hexagonal rings. We succeeded in the synthesis of a dibenzopentalene-linking polymer through C–C bonds between the pentagonal carbon atoms from 5,10-dibromodibenzopentalene under the two-zone chemical vapor deposition (2Z-CVD) and wet conditions. The resulting polymer was characterized by Raman spectroscopy. The present finding would spotlight the polymerization of a compound containing pentagonal moieties to introduce pentagonal units into carbon materials.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 46(8), 1099-1101, 2017

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130005906995
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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