UV-curable Thiol-ene Systems Composed of Dendritic Polyenes to Improve Photosensitivity

  • Aoki Ken'ichi
    Department of Chemistry, Graduate School of Science Department of Chemistry, Faculty of Science, Tokyo University of Science
  • Imanishi Ryota
    Development of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University

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Novel types of the dendritic polyenes with norbornene terminals (DNb(n), n = 8,16) were mixed with conventional six-armed polythiol (SH6) and photoinitiator (Ir-369) to obtain dendritic thiol-ene UV-curable materials in large scales. The photosensitivity of the norbornene-based dendritic resins was markedly improved by the activation of two types of polymerizations including thiol-ene polymerizations and radical-radical coupling.

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