Investigation of High Temperature Oxidation in Steam for Fe-Cr Alloy Using the Combination of a Hydrogen Sensor and an Oxygen Pump-Sensor
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- Fukumoto Michihisa
- Materials Science and Engineering Course, Department of Materials Science, Graduate School of Engineering Science, Akita University
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- Akabori Kouta
- Materials Science and Engineering Course, Department of Materials Science, Graduate School of Engineering Science, Akita University
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- Sonobe Hiroshi
- Materials Science and Engineering Course, Department of Materials Science, Graduate School of Engineering Science, Akita University
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- Hara Motoi
- Materials Science and Engineering Course, Department of Materials Science, Graduate School of Engineering Science, Akita University
Bibliographic Information
- Other Title
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- 水素センサーおよび酸素ポンプ・センサーを用いたFe-Cr合金の水蒸気酸化挙動の検討
- スイソ センサー オヨビ サンソ ポンプ ・ センサー オ モチイタ Fe-Cr ゴウキン ノ スイジョウキ サンカ キョドウ ノ ケントウ
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Abstract
<p>The water vapor oxidation behaviors of Fe and Fe-Cr alloys under isothermal and heat-cyclic conditions in an Ar-12 vol% H2O atmosphere were investigated by measuring both the hydrogen partial pressure using a hydrogen sensor and the oxidizing current of hydrogen using an oxygen pump-sensor, which were installed at the back section of the reactor. First, the performance of the oxygen pump-sensor was evaluated using Ar-1000 ppmH2 gas. As a result, it was found that the hydrogen concentration in the gas can be accurately measured by the oxidizing current of hydrogen. The isothermal oxidation test at 1173 K showed that the mass gain of the Fe-20 mass% Cr alloy was the highest, while the mass gain of the Fe-30 mass% Cr alloy was the lowest. For the Fe-20 mass% Cr alloy showing the highest mass gain, a rapid increase in the oxidation rate was observed during the oxidation test. The cyclic oxidation test indicated that the Fe and Fe-30 mass% Cr alloy had a lower oxidation rate in the second cycle than in the first cycle. On the contrary, for the Fe-20 mass% Cr alloy, the oxidation rate was higher in the second cycle than in the first cycle. For the Fe-30 mass% Cr alloy, the oxidation rate and mass gain during the cyclic oxidation test were low. The oxidation rates measured by the hydrogen sensor and the oxygen pump-sensor were showed the same behavior during the isothermal oxidation test. Since the oxidation rate is measured in situ using the hydrogen sensor and oxygen pump-sensor methods, it was clarified that both methods are effective for studying the water vapor oxidation behavior.</p>
Journal
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- Journal of the Japan Institute of Metals and Materials
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Journal of the Japan Institute of Metals and Materials 81 (9), 408-416, 2017
The Japan Institute of Metals and Materials
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Keywords
Details 詳細情報について
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- CRID
- 1390282681468462848
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- NII Article ID
- 130006003805
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- NII Book ID
- AN00187860
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- ISSN
- 18806880
- 24337501
- 00214876
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- NDL BIB ID
- 028509290
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed