Development of Batch and Flow Immobilized Catalytic Systems with High Catalytic Activity and Reusability

• Yamada Yoichi M. A.

  RIKEN Center for Sustainable Resource Science

抄録

My mission in catalysis research is to develop highly active and reusable supported catalytic systems in terms of fundamental chemistry and industrial application. For this purpose, I developed three types of highly active and reusable supported catalytic systems. The first type involves polymeric base-supported metal catalysts: Novel polymeric imidazole–Pd and Cu complexes were developed that worked at the mol ppm level for a variety of organic transformations. The second involves catalytic membrane-installed microflow reactors: Membranous polymeric palladium and copper complex/nanoparticle catalysts were installed at the center of a microtube to produce novel catalytic membrane-immobilized flow microreactor devices. These catalytic devices mediated a variety of organic transformations to afford the corresponding products in high yield within 1–38 s. The third is a silicon nanowire array-immobilized palladium nanoparticle catalyst. This device promoted a variety of organic transformations as a heterogeneous catalyst. The Mizoroki–Heck reaction proceeded with 280 mol ppb (0.000028 mol%) of the catalyst, affording the corresponding products in high yield.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 65 (9), 805-821, 2017

  公益社団法人 日本薬学会

キーワード

• supported catalyst
• microflow reactor
• silicon wafer
• catalytic system
• catalytic membrane

詳細情報

• CRID: 1390282679153467520
• NII論文ID: 130006038331
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.c17-00349
• ISSN: 13475223
• ISSN: 00092363
• NDL書誌ID: 028470106
• PubMed: 28867707
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I028470106
• Web Site: https://www.jstage.jst.go.jp/article/cpb/65/9/65_c17-00349/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
  • KAKEN
• 抄録ライセンスフラグ: 使用不可