Transition-metal Catalyzed Synthesis of Carbonyl Compounds Using Formates or Formamides as Carbonyl Sources

• Fujihara Tetsuaki

  Dept. of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

• Tsuji Yasushi

  Dept. of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

Bibliographic Information

Other Title

• 遷移金属錯体触媒を活用するギ酸エステルまたはホルムアミドを原料としたカルボニル化合物の合成反応

Abstract

Various available approaches for catalytic carbonylation reactions using formates and formamides with transition metal catalysts are reviewed. Pd complexes catalyze the hydroesterification or hydrocarbamoylation of alkynes using aryl formates or formamides, respectively, as the carbonyl sources. The esterification of aryl halides with aryl formates proceeds in the presence of a Pd catalyst with suitable ligands. Using a Cu complex with a bulky bidentate phosphine ligand is used as a catalyst, boraformylation and silaformylation of allenes efficiently proceeds using alkyl formates as a formyl source.

Journal

• Journal of the Japan Petroleum Institute

  Journal of the Japan Petroleum Institute 61 (1), 1-9, 2018-01-01

  The Japan Petroleum Institute

Keywords

• Formate
• Formamide
• Homogeneous catalysis
• Palladium
• Copper

Details

• CRID: 1390001205188556544
• NII Article ID: 130006301652
• NII Book ID: AA11590615
• DOI: 10.1627/jpi.61.1
• ISSN: 1349273X
• ISSN: 13468804
• NDL BIB ID: 028765502
• Web Site: http://id.ndl.go.jp/bib/028765502
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I028765502
• Web Site: https://www.jstage.jst.go.jp/article/jpi/61/1/61_1/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed