Estimating the In-use Degradation Mechanism of a Pre-oxidation Catalyst for Heavy-duty Urea-SCR Vehicles Complying with the New Long-term Target-based Regulation in Japan

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  • 新長期規制対応尿素SCR システム搭載重量車の使用過程における前段酸化触媒 の劣化メカニズムの推定
  • シン チョウキ キセイ タイオウ ニョウソ SCR システム トウサイ ジュウリョウシャ ノ シヨウ カテイ ニ オケル ゼンダン サンカ ショクバイ ノ レッカ メカニズム ノ スイテイ

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Abstract

Urea-SCR systems have been installed in heavy-duty vehicles for complying with the new long-term target-based regulation in Japan, contributing to reduce NOx emissions. However, in fiscal 2011, a survey of Ministry of the Environment, Japan reported in-use degradation of the systems in heavy-duty urea-SCR vehicles. In fiscal 2012, in-use degradation mechanisms of a SCR catalyst and ammonia slip catalyst were reported to be hydro carbon poisoning. On the other hand, the degradation mechanism of a pre-oxidation catalyst has been a remained issue in the urea-SCR systems. We studied the in-use degradation mechanism of a pre-oxidation catalyst in urea-SCR systems and revealed temperature and sulfur conditions impacting on the degradation.

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