Oxidation Resistance of Nickel Surface by Molecular Coating of Thiol-terminated Polymers

  • Yamakawa Kosuke
    Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology
  • Takagi Juri
    Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology
  • Nguyen Hai Thanh
    Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology
  • Adachi Kaoru
    Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology
  • Tsukahara Yasuhisa
    Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology

抄録

<p>Molecular coatings of thiol-terminated organic compounds such as thiol-terminated polystyrenes and alkanethiols were formed on nickel surfaces by means of interaction between nickel and thiol groups in order to investigate air oxidation resistance properties of the surface by the coatings. CV and LSV measurements indicate the organic layer prevents the nickel surface from both electrical oxidation and oxidation in air. Thiol-terminated polystyrene provides higher heat resistance than alkanethiols while maintaining electrical conductivity.</p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 47 (2), 119-121, 2018

    公益社団法人 日本化学会

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