Fabrication of TiO<sub>2</sub>/SiO<sub>2</sub> Composite Coating via a High-Temperature Self-Organizing Porous TiO<sub>2</sub> Layer on Ti

DOI Web Site Web Site 1 Citations 18 References Open Access
  • Miura-Fujiwara Eri
    Department of Materials and Synchrotron Radiation Engineering, Graduate School of Engineering, University of Hyogo Faculty of Materials Science and Chemistry, School of Engineering, University of Hyogo
  • Harada Hiroshi
    Department of Materials and Synchrotron Radiation Engineering, Graduate School of Engineering, University of Hyogo
  • Tanaka Yoshinobu
    Faculty of Materials Science and Chemistry, School of Engineering, University of Hyogo
  • Kikuchi Takeyuki
    Faculty of Materials Science and Chemistry, School of Engineering, University of Hyogo Department of Chemical Engineering and Materials Science, Graduate School of Engineering, University of Hyogo
  • Yamasaki Thoru
    Department of Materials and Synchrotron Radiation Engineering, Graduate School of Engineering, University of Hyogo Faculty of Materials Science and Chemistry, School of Engineering, University of Hyogo

Bibliographic Information

Other Title
  • 高温酸化による多層構造を利用した真空ゾルゲル法によるTiO<sub>2</sub>/SiO<sub>2</sub>複合被膜の創製
  • 高温酸化による多層構造を利用した真空ゾルゲル法によるTiO₂/SiO₂複合被膜の創製
  • コウオン サンカ ニ ヨル タソウ コウゾウ オ リヨウ シタ シンクウ ゾルゲルホウ ニ ヨル TiO ₂/SiO ₂ フクゴウ ヒマク ノ ソウセイ

Search this article

Abstract

<p>We studied the fabrication of a TiO2/SiO2 composite coating on Ti. At a temperature above 1100 K with oxygen partial pressure, a self-organized coating of rutile phase TiO2 is formed on a Ti substrate. The thick TiO2 coating (> 10 m) had a “piecrust-like” multilayer structure, which comprise TiO2 monolayers and gaps. A composite coating containing SiO2 was fabricated via a sol-gel method in vacuum to improve the exfoliation strength of the brittle, porous TiO2 coating. Cross-sectional SEM images revealed sufficient amounts of SiO2 in the gaps between the TiO2 monolayers in the TiO2/SiO2 composite coating, even at the interface between the oxide coating and the substrate. Exfoliation stress of the composite coating was up to 10–15 times higher than for the self-organized TiO2 coating alone, and the composite coating’s failure mode was interfacial compared with cohesive for the self-organized TiO2 coating.</p><p> </p><p>Mater. Trans. 57（2016） 2008-2014に掲載</p><p>本研究の背景をより正確にするため，実験方法，結果，考察の一部を修正し，文献の追加および順番を変更，Fig. 12を追加した．</p>

Journal

Citations (1)*help

See more

References(18)*help

See more

Related Projects

See more

Keywords

Details 詳細情報について

Report a problem

Back to top