“π-Figuration” for Controlling Stacking of π-Conjugated Molecules and Polymers

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  • π共役系分子および高分子の重なり方をデザインする『π造形科学』：酸化還元系を中心に
  • pキョウヤクケイ ブンシ オヨビ コウブンシ ノ カサナリ カタ オ デザイン スル 『 pゾウケイ カガク 』 : サンカ カンゲンケイ オ チュウシン ニ

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Abstract

<p>π-Conjugated molecules and polymers are expected to have a variety of applications in organic electronics. Control over how these π-conjugated systems stack in the solid state is crucial for utilization of their desirable photophysical and electrical properties. Some molecules need to be designed with enhanced π-stacking abilities, whereas others might display novel properties as a result of restricting their π-stacking abilities. Furthermore, π-conjugated molecules or polymers that display partial π-stacking are of interest for potential new applications because of the synergy of the contrasting properties of stacked and isolated π-conjugated systems. Here, we highlight recent progress in molecular design to control π-stacking, with a particularly focus on the redox properties of these unique molecular systems.</p>

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