Synthesis and Crystal Structure of Bis[2-(2-imidazolinyl)phenolato]copper(II)

• MITSUHASHI Ryoji

  Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University

• MIYAZAKI Yusuke

  Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University

• HOSOYA Satoshi

  Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University

• MIKURIYA Masahiro

  Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University

Abstract

The crystal structure of Cu(II) complex with 2-(2-imidazolinyl)phenolate was determined by X-ray crystallography. The title compound was synthesized by a reaction of Cu(NO₃)₂·3H₂O and 2-(2-imidazolinyl)phenolate in methanol. The compound crystallized in the monoclinic space group P2₁/c and Z = 2 with cell parameters a = 9.2964(9)Å, b = 10.4722(10)Å, c = 8.8271(9)Å, β = 112.0280(10)°, V = 796.62(14)ų. The R₁ [I > 2σ(I)] and wR₂ (all data) values are 0.0306 and 0.0844, respectively, for all 1943 independent reflections. In the crystal, a 2D sheet structure was formed by intermolecular hydrogen-bonds between the coordinating phenolate-O atom and a noncoordinating N–H bond.

Journal

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 34 (0), 11-12, 2018

  The Japan Society for Analytical Chemistry

Keywords

• Materials Chemistry
• Analytical Chemistry

Details

• CRID: 1390282680276039552
• NII Article ID: 130006471543
• DOI: 10.2116/xraystruct.34.11
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/34/0/34_11/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed