Measurement of Electron Transfer within a Single Supramolecular Assembly Containing a Biological Molecule

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  • KOZAKAI Takafumi
    Department of Chemistry, School of Science, Tokyo Institute of Technology
  • HARASHIMA Takanori
    Department of Chemistry, School of Science, Tokyo Institute of Technology
  • KIGUCHI Manabu
    Department of Chemistry, School of Science, Tokyo Institute of Technology
  • NISHINO Tomoaki
    Department of Chemistry, School of Science, Tokyo Institute of Technology

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Abstract

<p>We report on a method to measure the electron transport of a single molecular assembly by scanning tunneling microscopy (STM). The STM molecular tip together with a chemically modified substrate was utilized to form an assembly with a single target molecule. This method was successfully applied to a heme peptide to reveal the transport property of a single peptide-containing assembly. The present work opens a way to create functional single molecular devices using biomolecules.</p>

Journal

  • Analytical Sciences

    Analytical Sciences 34 (5), 521-523, 2018-05-10

    The Japan Society for Analytical Chemistry

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