Synthesis, Crystal Structure, and Relativistic DV-Xα Calculation of a μ-Oxido-μ-molybdato(VI)-bridged Dinuclear Oxidomolybdenum(V) Complex with 2-(3-Aminopropyl)aminoethanethiol

• MIKURIYA Masahiro

  School of Science and Technology, Kwansei Gakuin University

• KUSUNOKI Koji

  School of Science and Technology, Kwansei Gakuin University

• KOTERA Takanori

  School of Science and Technology, Kwansei Gakuin University

• YOSHIOKA Daisuke

  School of Science and Technology, Kwansei Gakuin University

• TAKEMURA Shota

  School of Science and Technology, Kwansei Gakuin University

• OGASAWARA Kazuyoshi

  School of Science and Technology, Kwansei Gakuin University

抄録

A μ-O-μ-Mo^VIO₄-bridged dinuclear oxidomolybdenum(V) complex with 2-(3-aminopropyl)aminoethanethiol (Hapaet), [Mo₃O₇(apaet)₂]·2CH₃OH, was prepared. The crystal structure was determined by the single-crystal X-ray diffraction method at 293 K. It crystallizes in the monoclinic space group P2₁/n with a = 16.558(3)Å, b = 8.9725(13)Å, c = 17.193(3)Å, β = 90.192(2)°, V = 2554.3(7)ų, D_x = 1.899 g/cm³, and Z = 4. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0331 and 0.0768, respectively, for all 6166 independent reflections. The two molybdenum atoms are bridged by an oxido-O atom and MoO₄²⁻ in a distorted octahedral geometry with oxido-O and meridional NNS-donor atoms of apaet⁻. A relativistic DV-Xα calculation supported the Mo^V₂Mo^VI mixed-valent state.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 34 (0), 19-21, 2018-04-10

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390282680276957696
• NII論文ID: 130006733655
• DOI: 10.2116/xraystruct.34.19
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/34/0/34_19/_pdf
• 本文言語コード: en
• データソース種別:
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  • KAKEN
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