Preparation of a Thermally Stable Room Temperature Ionic Liquid Containing Cage-Like Oligosilsesquioxane with Two Types of Side-Chain Groups
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- Harada Akiyuki
- Graduate School of Science and Engineering, Kagoshima University
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- Koge Sayako
- Graduate School of Engineering, Hiroshima University
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- Ohshita Joji
- Graduate School of Engineering, Hiroshima University
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- Kaneko Yoshiro
- Graduate School of Science and Engineering, Kagoshima University
Bibliographic Information
- Other Title
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- Selected Paper : Preparation of a Thermally Stable Room Temperature Ionic Liquid Containing Cage-Like Oligosilsesquioxane with Two Types of Side-Chain Groups
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Abstract
<p>A thermally stable room temperature ionic liquid containing cage-like oligosilsesquioxane (POSS) with two types of side-chain groups (Amim-Cage-SQ-IL) was successfully prepared by the hydrolytic condensation of a mixture of two organotrialkoxysilanes from which one contained a quaternary ammonium group trimethyl[3-(triethoxysilyl)propyl]ammonium chloride (TTACl) and the other an imidazolium group 1-methyl-3-[3-(triethoxysilyl)propyl]imidazolium chloride (MTICl). Moreover, superacid bis(trifluoromethanesulfonyl)imide (HNTf2) was used as a catalyst in water/methanol mixed solvent. Amim-Cage-SQ-IL exhibited a glass-transition temperature (Tg) of −8 °C as indicated by a baseline shift in the differential scanning calorimetry (DSC) curve. In addition, fluidity was visually observed at ca. 30 °C, i.e., Amim-Cage-SQ-IL is a room temperature ionic liquid. Because of the low molecular symmetry of the resulting POSS compound containing two different randomly distributed side-chain groups, its crystallization was suppressed, leading to the disappearance of the melting temperature (Tm). Consequently, Amim-Cage-SQ-IL exhibited low flow temperature. Moreover, the pyrolysis temperatures of Amim-Cage-SQ-IL were extremely high (its pyrolysis temperature of the 5% weight loss was 420 °C).</p>
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 89 (9), 1129-1135, 2016
The Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390282679118780672
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- NII Article ID
- 130006770694
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- NII Book ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- NDL BIB ID
- 027601679
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed