A Metal-Organic Framework Containing Arsenic Atoms with a Free Lone Pair

• Makoto Ishidoshiro

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585

• Hiroaki Imoto

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585

• Kensuke Naka

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585

抄録

A metal-organic framework (MOF) was constructed based on a 1,4-dihydro-1,4-diarsinine (DHDA) tetracarboxylic acid ligand, which was newly synthesized via hydrolysis of DHDA tetramethyl tetracarboxylate. The lone pairs of the arsenic atoms were not involved in the construction of the MOF. Notably, the preparation procedure of the MOF was performed under ambient atmosphere without any protecting groups, while inert atmosphere is required for incorporating trivalent phosphorus atoms.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 89 (9), 1057-1062, 2016-06-16

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644027166976
• NII論文ID: 130006770697
• DOI: 10.1246/bcsj.20160120
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/89/9/1057/56279775/bcsj.20160120.pdf
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