動的粘弾性による新しい架橋型熱可塑性エラストマーの評価方法の検討

DOI Web Site Web Site 参考文献11件

書誌事項

タイトル別名
  • New Testing Method for the Thermoplastic Vulcanization Processing Analysis by Dynamic Viscoelastic Properties
  • ドウテキネンダンセイ ニ ヨル アタラシイ カケハシガタ ネツ カソセイ エラストマー ノ ヒョウカ ホウホウ ノ ケントウ

この論文をさがす

抄録

<p>Thermoplastic elastomer (TPE) produced by dynamic vulcanization which is one of the reactive processing is generally called thermoplastic vulcanization (TPV). <br/>It is considered that, in the mixing process of TPV, the crosslink reaction and the EPDM dispersion in PP proceeds simultaneously. Therefore, the phase structure of TPV is complex and it is very difficult to analyze the kneading states. Since the slight difference of kneading states is known to lead to the large differences in the physical properties such as the extrusion processability and the surface appearance of the products, the conventional and exact testing methods to estimate TPV kneading state is required at TPV mixing plant. <br/>It was found that an apparent activation energy (Ea) calculated from the temperature dependence of dynamic viscosity modulus is an effective index for measuring the degree of crosslink. Also the degree of EPDM dispersion was quantified by dynamic elasticity modulus change ratio (Gr) between G* at the strain of 20% and 1%. These indices can be calculated simply and easily from dynamic viscoelastic results and can be applied to estimate the kneading state of the TPV compound.</p>

収録刊行物

  • 日本ゴム協会誌

    日本ゴム協会誌 90 (4), 183-189, 2017

    一般社団法人 日本ゴム協会

参考文献 (11)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ