A Theoretical Study on Radical-based Aminocarbonylation of Aryl Iodides

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Author(s)

    • Kawamoto Takuji
    • Department of Chemistry, Graduate School of Science, Osaka Prefecture University
    • Matsubara Hiroshi
    • Department of Chemistry, Graduate School of Science, Osaka Prefecture University
    • Fukuyama Takahide
    • Department of Chemistry, Graduate School of Science, Osaka Prefecture University
    • Ryu Ilhyong
    • Department of Chemistry, Graduate School of Science, Osaka Prefecture University|Department of Applied Chemistry, National Chiao Tung University

Abstract

<p>Aminocarbonylation of aromatic iodides with CO and amines gives aromatic amides under photoirradiation conditions. DFT calculations predict that methylamine adds to benzoyl radical to give a zwitterionic radical, which would afford the product <i>via</i> two pathways: (a) an amine-assisted proton transfer followed by a single electron transfer reaction (SET) with iodobenzene or (b) complexation with iodobenzene and then the SET.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 47(9), 1169-1171, 2018

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130007472138
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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