Highlighted Paper selected by Editor-in-Chief : Manganese-Catalyzed Oxophosphorylation Reaction of Carbon-Carbon Double Bonds Using Molecular Oxygen in Air

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  • Yamamoto Daisuke
    Laboratory of Organic Chemistry for Drug Development and Medicinal Research Laboratories, Graduate School of Pharmaceutical Sciences, Kitasato University
  • Ansai Hiromasa
    Laboratory of Organic Chemistry for Drug Development and Medicinal Research Laboratories, Graduate School of Pharmaceutical Sciences, Kitasato University
  • Hoshino Junichi
    Laboratory of Organic Chemistry for Drug Development and Medicinal Research Laboratories, Graduate School of Pharmaceutical Sciences, Kitasato University
  • Makino Kazuishi
    Laboratory of Organic Chemistry for Drug Development and Medicinal Research Laboratories, Graduate School of Pharmaceutical Sciences, Kitasato University

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  • Manganese-Catalyzed Oxophosphorylation Reaction of Carbon–Carbon Double Bonds Using Molecular Oxygen in Air

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<p>A novel aerobic manganese-catalyzed oxophosphorylation reaction of carbon–carbon double bonds of styrene derivatives and vinyl ethers using diethyl H-phosphonates was developed. This direct transformation of alkenes to β-ketophosphonate readily proceeded at room temperature via the direct incorporation of molecular oxygen present in air (open flask).</p>

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