Generation of Active Ruthenium Catalysts for Hydroarylation of C-C Multiple Bonds from Isolated Ru(Ⅳ)=O Species Supported on CeO₂

• Hiroki Miura

• Masahiro Nagao

• Saburo Hosokawa

• Tetsuya Shishido

• Masashi Inoue

• Kenji Wada

抄録

This paper reports that the treatment of Ru/CeO2 with PPh3 and HCHO in 2-methoxyalcohol was an efficient way to generate the catalytically active Ru species for hydroarylation of C-C multiple bonds. A variety of alkenes was applicable toward the title reactions. The solid Ru/CeO2 could be recycled for several times.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 91 (9), 1397-1401, 2018-09

  Tokyo : Chemical Society of Japan

キーワード

• Ruthenium
• Hydroarylation
• Solid catalyst

詳細情報

• CRID: 1521136280691822336
• NII論文ID: 130007484160
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.20180144
• NDL書誌ID: 029212215
• Web Site: http://id.ndl.go.jp/bib/029212215
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I029212215
• Web Site: https://academic.oup.com/bcsj/article-pdf/91/9/1397/56293438/bcsj.20180144.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN