Crystal Structure of a Mononuclear Iron(III) Complex, Dichloridobis(1,10-phenanthroline-κ²<i>N,N</i>′)iron(III) Hexafluoridophosphate–acetonitrile

• KANEKO Satoshi

  Department of Science, Faculty of Science, Yamagata University

• MITSUHASHI Ryoji

  Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University

• MIKURIYA Masahiro

  Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University

• SAKIYAMA Hiroshi

  Department of Science, Faculty of Science, Yamagata University

抄録

A mononuclear iron(III) complex, [FeCl₂(phen)₂][PF₆]·MeCN [dichloridobis(1,10-phenanthroline-κ²N,N′)iron(III) hexafluoridophosphate–acetonitrile], was synthesized, and characterized by single-crystal X-ray method. The compound crystallized in the monoclinic space group C2/c and Z = 4 with cell parameters a = 16.3586(12)Å, b = 12.6022(9)Å, c = 13.0231(9)Å, β = 103.6760(10)°, V = 2608.7(3)ų. The R₁ [I > 2σ(I)] and wR₂ (all data) values were 0.0345 and 0.0949, respectively, for all 3161 independent reflections. Analysis revealed that the complex cation has an octahedral coordination geometry with a Cl₂N₄ donor set with two chloride ligands at the cis-positions.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 34 (0), 49-50, 2018-10-10

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390001288082541056
• NII論文ID: 130007496621
• DOI: 10.2116/xraystruct.34.49
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/34/0/34_49/_pdf
• 本文言語コード: en
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