Crystal Structure of Bis(μ-hydroxo)diiron(II) Complex with a Dinucleating Ligand Having a Butyl Linker

• SEKINO Mio

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

• FURUTACHI Hideki

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

• TASAKI Kyosuke

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

• ISHIKAWA Takanao

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

• FUJINAMI Shuhei

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

• AKINE Shigehisa

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University Nano Life Science Institute (WPI-NanoLSI), Kanazawa University

• SAKATA Yoko

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

• SUZUKI Masatatsu

  Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

• NOMURA Takashi

  Picobiology Institute, Graduate School of Life Science, University of Hyogo

• OGURA Takashi

  Picobiology Institute, Graduate School of Life Science, University of Hyogo

• KITAGAWA Teizo

  Picobiology Institute, Graduate School of Life Science, University of Hyogo

抄録

The structure of the dinuclear Fe(II) complex [Fe₂(OH)₂(L^Bu)]²⁺ (1) was determined by X-ray crystallography, where L^Bu is N,N,N′,N′-tetrakis(6-methyl-2-pyridylmethyl)-1,4-diaminobutane. The compound crystallizes in a monoclinic space group, P2₁/a, with a = 21.678(3), b = 16.3791(16), c = 22.447(3)Å, β = 111.522(2)°, Z = 4, V = 7414.5(14)ų. The R1 [I > 2σ(I)] and wR2 (all data) values were 0.0474 and 0.1274, respectively, for all 16779 independent reflections. The complex has a bis(μ-hydroxo)diiron core structure.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 35 (0), 5-7, 2019-02-10

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390564238075423744
• NII論文ID: 130007595833
• DOI: 10.2116/xraystruct.35.5
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/35/0/35_5/_pdf
• 本文言語コード: en
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