Synthesis of Phosphole-bridged Porphyrin Dimers

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著者

    • Higashino Tomohiro
    • Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
    • Nishimura Issei
    • Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
    • Imahori Hiroshi
    • Department of Molecular Engineering, Graduate School of Engineering, Kyoto University|Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto Univeristy

抄録

<p>We synthesized phosphole-bridged porphyrin dimers and evaluated their optical and electrochemical properties. The porphyrin dimers exhibited broadened and red-shifted absorption relative to thienylene- and <i>p</i>-phenylene-bridged reference dimers, suggesting effective π-conjugation between the porphyrins through the phosphole linker. The more positive reduction potentials of phosphole-bridged porphyrin dimers compared to reference dimers are attributed to the electron-accepting ability of the phosphole linker.</p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 48(3), 257-259, 2019

    公益社団法人 日本化学会

各種コード

  • NII論文ID(NAID)
    130007607563
  • 本文言語コード
    ENG
  • ISSN
    0366-7022
  • データ提供元
    J-STAGE 
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