Amino Amide Organocatalysts for Asymmetric Michael Addition of β-Keto Esters with β-Nitroolefins

• オウォラビ, イシアカ アラデ

• チェンアプラム, マデュー

• 関, 千草

• 奥山, 祐子

• 權, 垠相

• 上井, 幸司

• 常盤, 峻士

• 竹下, 光弘

• 中野, 博人

抄録

Asymmetric Michael addition of β-keto esters with trans-β-nitroolefins using chiral amino amide organocatalyst was tried and afforded synthetically useful chiral Michael adducts in both excellent chemical yields (up to 99%) and stereoselectivities (up to dr. 99:1, up to 98% ee).

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 92 (3), 696-701, 2019

  Bulletin of the Chemical Society of Japan

キーワード

• Amino amide
• Organocatalyst
• Michael naddition

詳細情報

• CRID: 1050282677541149184
• NII論文ID: 130007611965
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.20180302
• ISSN: 13480634
• ISSN: 00092673
• HANDLE: 10258/00009895
• Web Site: https://muroran-it.repo.nii.ac.jp/records/9947
• Web Site: https://academic.oup.com/bcsj/article-pdf/92/3/696/56298300/bcsj.20180302.pdf
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • Crossref
  • CiNii Articles