Magnetic Switching by Desorption/Adsorption of an Organic Solvent Molecule from/on [Ni(dmit)<sub>2</sub>]<sup>−</sup> Salt

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Author(s)

    • Nishimura Takumi
    • Department of Chemistry, Graduate School of Science, Hiroshima University
    • Konno Daisuke
    • Department of Chemistry, Graduate School of Science, Hiroshima University
    • Inoue Katsuya
    • Department of Chemistry, Graduate School of Science, Hiroshima University|Chirality Research Center (CResCent) and Institute for Advanced Materials Research, Hiroshima University
    • Nakaya Toshimi
    • Department of Applied Chemistry, Graduate School of Engineering and Technical Center, Hiroshima University
    • Akutagawa Tomoyuki
    • Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
    • Nishihara Sadafumi
    • Department of Chemistry, Graduate School of Science, Hiroshima University|Chirality Research Center (CResCent) and Institute for Advanced Materials Research, Hiroshima University

Abstract

<p>Herein, the synthesis and physical properties of a monovalent [Ni(dmit)<sub>2</sub>]<sup>−</sup> salt (dmit<sup>2−</sup> = 2-thioxo-1,3-dithiole-4,5-dithiolate) containing a supramolecular cation composed of Na<sup>+</sup> ions, dibenzo[18]crown-6 molecules, and CH<sub>3</sub>CN molecules, has been reported. The desorption/adsorption of CH<sub>3</sub>CN molecules (organic solvent molecules) from/on the [Ni(dmit)<sub>2</sub>]<sup>−</sup> salt occurred while maintaining the crystalline state and could be utilized to switch the magnetic properties of the salt.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 48(4), 329-332, 2019

    The Chemical Society of Japan

Codes

  • NII Article ID (NAID)
    130007624436
  • Text Lang
    ENG
  • ISSN
    0366-7022
  • Data Source
    J-STAGE 
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