Crystal Structure of Bis(μ-hydroxo)diiron(III) Complex with Tripodal Ligands Having a Terminal Carboxylate Group
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- ZHANG Xi
- Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
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- FURUTACHI Hideki
- Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
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- OHYAMA Yuya
- Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
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- FUJINAMI Shuhei
- Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
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- AKINE Shigehisa
- Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University Nano Life Science Institute (WPI-NanoLSI), Kanazawa University
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- SUZUKI Masatatsu
- Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
抄録
<p>The structure of the dinuclear Fe(III) complex [Fe2(6Me2-BPP)2(OH)2](NO3)1.9553·Br0.0447·8H2O (1) was determined by X-ray crystallography, where 6Me2-BPP is N,N-bis(6-methyl-2-pyridylmethyl)-3-aminopropionate. The compound crystallizes in a triclinic space group, P1, with a = 10.3845(15), b = 11.1976(15), c = 20.389(4)Å, α = 82.119(10), β = 85.340(10), γ = 68.871(7)°, Z = 2, V = 2189.3(6)Å3. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0342 and 0.0972, respectively, for all 9586 independent reflections. The complex has a bis(μ-hydroxo)diiron core structure.</p>
収録刊行物
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- X-ray Structure Analysis Online
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X-ray Structure Analysis Online 35 (0), 17-19, 2019-04-10
社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390564238083691904
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- NII論文ID
- 130007630338
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- ISSN
- 18833578
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- 本文言語コード
- en
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