Rhodium(III)-Catalyzed β-Arylation and -Alkenylation of α-Trifluoromethylacrylic Acid

• Yoshimoto, Risa

• Usuki, Yoshinosuke

• Satoh, Tetsuya

Abstract

The β-arylation and -alkenylation of trifluoromethylacrylic acid with arylboronic acids and alkenes proceed smoothly under rhodium(III) catalysis. The procedures provide useful synthetic routes from readily available building brocks to β-aryl-α-trifluoromethylpropanoic acid and 5,5,5-trifluoro-1,3-butadiene derivatives. Some of the obtained butadienes exhibit strong fluorescence in the solid state.

Journal

• Chemistry Letters

  Chemistry Letters 48 (5), 461-464, 2019-02-05

  Chemical Society of Japan

Keywords

• ロジウム触媒
• アリール化
• 有機フッ素化合物
• rhodium catalyst
• arylation
• alkenylation
• organofluorine compound

Details

• CRID: 1050002212664565248
• NII Article ID: 130007642580
• NII Book ID: AA12179675
• ISSN: 13480715
• ISSN: 03667022
• DOI: 10.1246/cl.190024
• Web Site: https://dlisv03.media.osaka-cu.ac.jp/il/meta_pub/G0000438repository_13480715-48-5-461
• Web Site: http://www.journal.csj.jp/doi/pdf/10.1246/cl.190024
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • Crossref
  • CiNii Articles
  • KAKEN