Synthesis and Crystal Structure of 1,3-Bis(5-chloro-3-methoxysalicylideneamino)-2-propanol Trihydrate

• MIKURIYA Masahiro

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University

• KOYAMA Yoshiki

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University

• MITSUHASHI Ryoji

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University

Abstract

The title compound, 1,3-bis(5-chloro-3-methoxysalicylideneamino)-2-propanol trihydrate, was synthesized and the crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. It crystallizes in the monoclinic space group P2/c with a = 18.098(3)Å, b = 4.3275(8)Å, c = 14.572(3)Å, β = 104.283(3)°, V = 1106.0(3)ų, D_x = 1.445 g/cm³, and Z = 2. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0734 and 0.2140, respectively, for all 2540 independent reflections. The molecule takes a bended structure at the central carbon atom with a dihedral angle between the two approximate planes of 74.71°.

Journal

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 35 (0), 33-34, 2019-05-10

  The Japan Society for Analytical Chemistry

Keywords

• Materials Chemistry
• Analytical Chemistry

Details

• CRID: 1390845713065765504
• NII Article ID: 130007644429
• DOI: 10.2116/xraystruct.35.33
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/35/0/35_33/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed