Synergistic <i>N</i>-Heterocyclic Carbene/Palladium-Catalyzed Allylation of Aldehydes with Allylic Carbonates

• Shunsuke Takemoto

  Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 , Japan

• Takuya Ishii

  Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 , Japan

• Shigeo Yasuda

  Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 , Japan

• Hirohisa Ohmiya

  Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 , Japan

抄録

The synergistic merger of a thiazolium N-heterocyclic carbene (NHC) catalyst and a palladium–bisphosphine catalyst enabled the allylation of aldehyde acyl anions using allylic carbonates as electrophiles. Owing to the mildness of the reaction conditions, various functional groups were tolerated in the substrates.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 92 (5), 937-940, 2019-02-14

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360567186941464960
• NII論文ID: 130007649755
• DOI: 10.1246/bcsj.20190012
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/92/5/937/56294693/bcsj.20190012.pdf
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