Crystal Structure of [<i>N</i>-(9-Anthracenylmethyl)-1,3-propanediamine](2,2′-bipyridine)platinum(II) Chloride

• KIWADA Tatsuto

  Faculty of Pharmacy, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University

• TAKAYAMA Hiroshi

  Department of Chemistry, Graduate School of Science, Nagoya University

• KATAKASU Hiromu

  School of Pharmaceutical Sciences, College of Medical, Pharmaceutical and Health Sciences, Kanazawa University

• ODANI Akira

  Faculty of Pharmacy, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University

抄録

The crystal structure of [N-(9-anthracenylmethyl)-1,3-propanediamine](2,2′-bipyridine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group P21/c and Z = 4 with cell parameters a = 11.2466(7)Å, b = 17.3553(10)Å, c = 13.7027(9)Å, β = 100.501(2)°, V = 2629.8(3)ų. The R₁ [I > 2σ(I)] and wR₂ (all data) values are 0.0271 and 0.0619, respectively, for all 5995 independent reflections. The intramolecular π-π stacking interaction was observed between the anthracene and the bipyridine. In the crystal packing structure, the intermolecular π-π stacking interaction was observed.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 35 (0), 39-41, 2019-07-10

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390001288152590720
• NII論文ID: 130007677280
• DOI: 10.2116/xraystruct.35.39
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/35/0/35_39/_pdf
• 本文言語コード: en
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