A Theoretical Basis for the Enhancement of Seebeck Coefficients in Supramolecular Thermocells
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- Yimin Liang
- Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 , Japan
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- Hongyao Zhou
- Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 , Japan
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- Teppei Yamada
- Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 , Japan
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- Nobuo Kimizuka
- Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 , Japan
抄録
<jats:title>Abstract</jats:title> <jats:p>Seebeck coefficients (Se) of supramolecular thermocells harnessing four kinds of cyclodextrins as host molecules were investigated. Theoretical analysis revealed that association enthalpy between the hosts and triiodide has a major influence on the Seebeck coefficients of the thermocells. Thermodynamic parameters of host–guest associations were evaluated by isothermal titration calorimetry, which is in good agreement with the theoretically estimated values from thermocell measurements. This result provides a guideline to estimate Seebeck coefficient of supramolecular thermocells and to determine the thermodynamic parameters.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 92 (7), 1142-1147, 2019-05-18
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360846644027259776
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- NII論文ID
- 130007679367
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- ISSN
- 13480634
- 00092673
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