Crystal Structure of a Mononuclear Iron(II) Complex, Tris(1,10-phenanthroline-κ²<i>N,N</i>′)iron(II) Bis(hexafluoridophosphate)

• HOSHIKAWA Ryusei

  Department of Science, Faculty of Science, Yamagata University

• MITSUHASHI Ryoji

  Institute of Liberal Arts and Science, Kanazawa University

• MIKURIYA Masahiro

  Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University

• SAKIYAMA Hiroshi

  Department of Science, Faculty of Science, Yamagata University

抄録

A mononuclear iron(II) complex, [Fe(phen)₃][PF₆]₂ [tris(1,10-phenanthroline-κ²N, N′)iron(II) tris(hexafluoridophosphate)], was synthesized, and characterized by a single-crystal X-ray method. The compound crystallized in the monoclinic space group C2/c and Z = 8 with cell parameters a = 36.529(4)Å, b = 15.8597(16)Å, c = 11.7747(12)Å, β = 100.528(2)°, V = 6706.7(12)ų. The R₁ [I > 2σ(I)] and wR₂ (all data) values were 0.0631 and 0.1787, respectively, for all 8068 independent reflections. Despite the symmetrical tris(1,10-phenanthroline) environment, the symmetry around the iron(II) ion was rather low with a distorted octahedral coordination geometry.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 35 (0), 67-68, 2019-11-10

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390845702321228416
• NII論文ID: 130007743167
• DOI: 10.2116/xraystruct.35.67
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/35/0/35_67/_pdf
• 本文言語コード: en
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