<i>N</i>-Heterocyclic Carbene Ligands Having Planar Chiral Ferrocene Structure

• Yoshida Kazuhiro

  Department of Chemistry, Graduate School of Science, Chiba University

• Yasue Risa

Bibliographic Information

Other Title

• フェロセン骨格をもつ面性不斉含窒素複素環カルベン配位子

Abstract

Ferrocene, a prototypical sandwich compound, has attracted the attention of chemists since its discovery in 1951. The application of its unique structure as chiral phosphine ligand in transition metal catalysis is one of the most successful examples of ferrocene chemistry. Concurrent with these developments, N-heterocyclic carbene (NHC) ligands, which have characteristics different from phosphine ligands, have emerged as an indispensable tool in transition metal catalysis. What kind of ligand would be generated by combining a ferrocene and an NHC in one molecule? This review summarizes advances in this field that has started at the beginning of this century, focusing on planar-chiral, ferrocene-based NHC ligands.

Journal

• Journal of Synthetic Organic Chemistry, Japan

  Journal of Synthetic Organic Chemistry, Japan 78 (1), 28-40, 2020-01-01

  The Society of Synthetic Organic Chemistry, Japan

Keywords

• asymmetric catalysis
• chiral ligands
• ferrocene
• <i>N</i>-heterocyclic carbene
• planar chirality

Details

• CRID: 1390002184862275072
• NII Article ID: 130007783804
• DOI: 10.5059/yukigoseikyokaishi.78.28
• ISSN: 18836526
• ISSN: 00379980
• Web Site: https://www.jstage.jst.go.jp/article/yukigoseikyokaishi/78/1/78_28/_pdf
• Text Lang: ja
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed