Preparation and Crystal Structure of Sodium Tetraperoxidochromate(V)
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- MIKURIYA Masahiro
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- HIROSHIMA Shuichi
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- KOYAMA Yoshiki
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- TERADA Keisuke
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- YOSHIOKA Daisuke
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- MITSUHASHI Ryoji
- Institute of Liberal Arts and Science, Kanazawa University
Abstract
<p>Sodium tetraperoxidochromate(V), Na3Cr(O2)4·14H2O, was prepared and the crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. It crystallizes in the triclinic space group P1 with a = 7.5349(6)Å, b = 8.6378(7)Å, c = 8.9921(7)Å, α = 64.087(1), β = 81.565(1), γ = 69.348(1)°, V = 492.56(7)Å3, Dx = 1.690 g/cm3, and Z = 1. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0277 and 0.0722, respectively, for all 2310 independent reflections. The chromium ion is coordinated by four peroxido ligands in a distorted dodecahedral geometry, whereas each sodium ion is coordinated by six water molecules to form an octahedral Na(H2O)6 unit, which is connected by two bridging water molecules to form zigzag [cis-{Na(H2O)2(μ-H2O)4}-trans-{Na(H2O)2(μ-H2O)4}]n chain molecules in the crystal.</p>
Journal
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- X-ray Structure Analysis Online
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X-ray Structure Analysis Online 36 (0), 3-5, 2020-02-10
The Japan Society for Analytical Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390565134827021184
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- NII Article ID
- 130007796323
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- ISSN
- 18833578
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed