Selective Oxidative Hydroxylation of Arylboronic Acids by Colloidal Nanogold Catalyzed In Situ Generation of H2O2 from Alcohols under Aerobic Conditions

• Vinsen

  Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 , Japan

• Yuta Uetake

  Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 , Japan

• Hidehiro Sakurai

  Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 , Japan

抄録

Selective hydroxylation of arylboronic acids was achieved through PVP (polyvinylpyrrolidone)-stabilized nanogold catalyzed in situ generated H2O2 formed by the oxidation of an alcoholic solvent under aerobic conditions. The synthetic application of in situ generated H2O2 was investigated through aerobic epoxidation of (E)-chalcone.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 93 (2), 299-301, 2019-12-18

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219097150976
• NII論文ID: 130007798338
• DOI: 10.1246/bcsj.20190265
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/93/2/299/56302846/bcsj.20190265.pdf
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