FURFURAL PRODUCTION FROM XYLOSE AND BAMBOO POWDER OVER PROTON-EXCHANGED MONTMORILLONITE CLAYS IN TOLUEN-WATER BIPHASIC SOLVENT

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  • Yamauchi Yuki
    Chemistry Course, Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University
  • Nanao Hidetaka
    Chemistry Course, Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University
  • Sato Osamu
    Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST)
  • Yamaguchi Aritomo
    Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST)
  • Shirai Masayuki
    Chemistry Course, Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST)

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  • FURFURAL PRODUCTION FROM XYLOSE AND BAMBOO POWDER OVER PROTON-EXCHANGED MONTMORILLONITE CLAYS IN TOLUENE–WATER BIPHASIC SOLVENT

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<p>Furfural production from xylose and bamboo powder over proton-exchanged reference clays of The Clay Science Society Japan (JCSS-3101, JCSS-3102), and a commercially available clay (K10) in water–toluene biphasic solvent was studied. The three JCSS-3101, JCSS-3102, and K10 catalysts were active for the dehydration of xylose to furfural. The activities of JCSS-3101 and JCSS-3102 were lower than that of K10. Proton-exchanging treatment enhanced the furfural yields for the three JCSS-3101, JCSS-3102, and K10 catalysts. The dehydration behaviors were almost the same and 55% yields were obtained over the three proton-exchanged clays water–toluene biphasic solvent at 413 K for 24 h.</p>

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