Breathing New Life into Nonalternant Hydrocarbon Chemistry: Syntheses and Properties of Polycyclic Hydrocarbons Containing Azulene, Pentalene, and Heptalene Frameworks

• Akihito Konishi

  Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 , Japan

• Makoto Yasuda

  Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 , Japan

抄録

Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons. Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles, have engaged chemists’ attention for some time. In this review, we describe the salient revivals of these nonalternant hydrocarbons that are incorporated into polycyclic π-systems. Historical landmarks, recent studies, and fundamental properties, as well as potential applications to functional organic materials, are documented.

収録刊行物

• Chemistry Letters

  Chemistry Letters 50 (1), 195-212, 2020-12-29

  Oxford University Press (OUP)

詳細情報

• CRID: 1361694371937633024
• NII論文ID: 130007965983
• DOI: 10.1246/cl.200650
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/50/1/195/56758425/cl.200650.pdf
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