Crystal Structure of a μ-Phenolato-μ-oxido-bridged Dinuclear Manganese(III) Complex with Dinucleating Schiff-base Ligand Having Three Phenolate Groups
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- MIKURIYA Masahiro
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- ONO Sayuri
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- KOYAMA Yoshiki
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
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- MITSUHASHI Ryoji
- Institute of Liberal Arts and Science, Kanazawa University
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- TSUBOI Motohiro
- Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University
Abstract
<p>A μ-phenolato-μ-oxido-bridged dinuclear manganese(III) complex with 2-(5-nitro-2-hydroxyphenyl)-1,3-bis(2-(5-nitro-2-hydroxybenzylideneamino)ethyl)imidazolidine (H3LNO2) was synthesized. The crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. The complex crystallized as [(C2H5)3NH][Mn2(μ-LNO2)(μ-O)Cl2]·2THF in the orthorhombic space group Pnma with a = 15.052(3), b = 20.449(4), c = 14.700(3)Å, V = 4524.5(16)Å3, Dcalcd = 1.518 g/cm3, Z = 4. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0713 and 0.1700, respectively, for all 5336 independent reflections. The two manganese(III) atoms are bridged by a phenolato-oxygen atom of LNO23− and a μ-oxido-oxygen atom, where each manganese(III) atom is further coordinated by phenolato-oxygen, imino- and imidazolidine-nitrogen atoms of LNO23− in a meridional fashion and a chlorido ligand to form a distorted octahedral geometry.</p>
Journal
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- X-ray Structure Analysis Online
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X-ray Structure Analysis Online 37 (0), 3-5, 2021-01-10
The Japan Society for Analytical Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390568456351312000
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- NII Article ID
- 130007966982
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- ISSN
- 18833578
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed