Geodesic Phenine Frameworks

• Koki Ikemoto

  Department of Chemistry, The University of Tokyo, Hongo, Tokyo 113-0033 , Japan

• Hiroyuki Isobe

  Department of Chemistry, The University of Tokyo, Hongo, Tokyo 113-0033 , Japan

Abstract

The planar trigonal structure of 1,3,5-trisubstituted benzene, named phenine, has been adopted as basic units of polygonal networks to shape nanometer-sized curved organic π-molecules. The phenine design allows for concise syntheses of large carbonaceous molecules reaching 4 kDa by stitching geodesic lines with aryl coupling reactions. In this Account, the development of the defective nanocarbon molecules, i.e., geodesic phenine frameworks, is summarized to overview unique structural/electronic features.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 94 (1), 281-294, 2020-09-29

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1361975846893932544
• NII Article ID: 130007968760
• DOI: 10.1246/bcsj.20200284
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/94/1/281/56308013/bcsj.20200284.pdf
• Data Source:
  • Crossref
  • CiNii Articles
  • KAKEN