Dinuclear Rhombic Copper(I) Iodide Complexes with Rigid Bidentate Arsenic Ligands

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  • Ryosuke Kobayashi
    Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan
  • Hyota Kihara
    Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan
  • Takahiro Kusukawa
    Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan
  • Hiroaki Imoto
    Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan
  • Kensuke Naka
    Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan

抄録

<jats:title>Abstract</jats:title> <jats:p>We have recently developed a series of arsenic ligands based on practical synthetic strategies. Herein, three kinds of bidentate arsenic ligands with rigid linkers were selected to construct dinuclear rhombic copper(I) iodide (CuI) complexes, whose structures were analyzed by X-ray crystallography. They had sufficient solubility in organic solvents, and it was confirmed that their coordination forms were kept in the solutions. Intense solid-state emissions were observed even at room temperature, and the emission colors were varied from yellow to red by the ligands.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 50 (2), 382-385, 2020-12-03

    Oxford University Press (OUP)

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