Dinuclear Rhombic Copper(I) Iodide Complexes with Rigid Bidentate Arsenic Ligands

• Ryosuke Kobayashi

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan

• Hyota Kihara

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan

• Takahiro Kusukawa

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan

• Hiroaki Imoto

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan

• Kensuke Naka

  Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585 , Japan

Abstract

We have recently developed a series of arsenic ligands based on practical synthetic strategies. Herein, three kinds of bidentate arsenic ligands with rigid linkers were selected to construct dinuclear rhombic copper(I) iodide (CuI) complexes, whose structures were analyzed by X-ray crystallography. They had sufficient solubility in organic solvents, and it was confirmed that their coordination forms were kept in the solutions. Intense solid-state emissions were observed even at room temperature, and the emission colors were varied from yellow to red by the ligands.

Journal

• Chemistry Letters

  Chemistry Letters 50 (2), 382-385, 2020-12-03

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360850166934684160
• NII Article ID: 130007986380
• DOI: 10.1246/cl.200763
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/50/2/382/56297769/cl.200763.pdf
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