Crystal Structure of [11,14,17,110,51,54,57,510-Octaaza-1,5(1,4)-dicyclododecana-3,7(1,3)-dibenzenacyclooctaphane]zinc(II) tetrakis(nitrate), [m, m-bis(ZnII-cyclen)](NO3)4

• ICHIMARU Yoshimi

  College of Pharmacy, Kinjo Gakuin University

• JIN Wanchun

  College of Pharmacy, Kinjo Gakuin University

• YAMAGUCHI Yoshihiro

  Environmental Safety Center, Kumamoto University

• SUGIURA Kirara

  College of Pharmacy, Kinjo Gakuin University

• IMAI Masanori

  College of Pharmacy, Kinjo Gakuin University

• KUROSAKI Hiromasa

  College of Pharmacy, Kinjo Gakuin University

• FUJIOKA Haruto

  Laboratory of Organic Medicinal Chemistry, Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University

• KOIKE Tohru

  Department of Functional Molecular Science, Institute of Biochemical & Health Sciences, Hiroshima University

• HIEDA Yuhzo

  Laboratory of Organic Medicinal Chemistry, Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University

• KATO Koichi

  College of Pharmacy, Kinjo Gakuin University

書誌事項

タイトル別名

• Crystal Structure of [1¹,1⁴,1⁷,1¹⁰,5¹,5⁴,5⁷,5¹⁰-Octaaza-1,5(1,4)-dicyclododecana-3,7(1,3)-dibenzenacyclooctaphane]zinc(II) tetrakis(nitrate), [<i>m,m</i>-bis(Zn^II-cyclen)](NO₃)₄

抄録

The crystal structure of [1¹,1⁴,1⁷,1¹⁰,5¹,5⁴,5⁷,5¹⁰-octaaza-1,5(1,4)-dicyclododecana-3,7(1,3)-dibenzenacyclooctaphane]zinc(II) tetrakis(nitrate), [m,m-bis(Zn^II-cyclen)](NO₃)₄·4H₂O was determined by the single-crystal X-ray diffraction method at 93.15 K. The titled complex crystallized in the trigonal space group P3₁21 and Z = 3 with a = 8.97880(10), c = 44.4258(6)Å, and V = 3101.72(8)ų. The R₁ [I > 2σ(I)] and wR₂ (all data) values were 0.0250 and 0.0623, respectively, for all 3323 independent reflections. In the crystal structure, the Zn^II center is coordinated with two secondary amines, two tertiary amines, and nitrate to form a square pyramidal geometry. Two nitrate anions were coordinated with the respective Zn^II. The hydrogen bond network between the nitrate anion and water connects each m,m-bis(Zn^II-cyclen) complex.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 37 (0), 15-16, 2021-03-10

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390850247497094656
• NII論文ID: 130007996645
• DOI: 10.2116/xraystruct.37.15
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/37/0/37_15/_pdf
• 本文言語コード: en
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