Transition-metal Complexes with Triple Bonds to Si, Ge, Sn, and Pb and Relevant Complexes

• Hisako Hashimoto

  Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki, Aoba-ku, Sendai, Miyagi 980-8578 , Japan

• Koichi Nagata

  Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki, Aoba-ku, Sendai, Miyagi 980-8578 , Japan

抄録

Transition-metal complexes featuring triple bonds to heavier Group 14 elements (Si, Ge, Sn, and Pb), which have long been synthetic challenges in organometallic chemistry, have been synthesized in the last few decades. In this highlight, synthetic methods for numerous kinds of complexes and their structural properties are overviewed. Application leading to new multiple bonded systems with M≡Ge–Ge≡M, M≡Si–M, and M=Si=M linkages, and to relevant metallotetrylenes are also highlighted.

収録刊行物

• Chemistry Letters

  Chemistry Letters 50 (4), 778-787, 2021-01-09

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360287706363506304
• NII論文ID: 130008025754
• DOI: 10.1246/cl.200872
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/50/4/778/56320544/cl.200872.pdf
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