Organic-Inorganic Hybrid Molecular Architectures Utilizing Self-assembled Monolayers for Singlet Fission and Light Energy Conversion

  • Taku Hasobe
    Faculty of Science and Technology, Keio University, Yokohama, Kanagawa 223-8522 , Japan

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<jats:title>Abstract</jats:title> <jats:p>Organic-inorganic hybrid molecular architectures utilizing self-assembled monolayers (SAMs) of organic chromophores (e.g., acene derivatives) are systematically discussed to examine the photophysical properties together with covalently-linked dimeric and oligomeric forms. Multi-exciton generation (i.e., singlet fission) and light energy conversion processes that occur in a reaction site composed of chemically modified organic chromophores on the surface of inorganic nanomaterials such as gold nanocluster, gold nanorod and quantum dot are described.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 50 (4), 615-622, 2021-03-27

    Oxford University Press (OUP)

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