Determination of Chemical Structure of Bis(dithiolato)iron Nanosheet

• Choon Meng Tan

  Research Center for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 , Japan

• Mami Horikawa

  Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 , Japan

• Naoya Fukui

  Research Center for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 , Japan

• Hiroaki Maeda

  Research Center for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 , Japan

• Sono Sasaki

  Faculty of Fibre Science and Engineering, Kyoto Institute of Technology, Kyoto 606-8585 , Japan

• Kazuhito Tsukagoshi

  WPI International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044 , Japan

• Hiroshi Nishihara

  Research Center for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510 , Japan

抄録

Liquid-liquid interfacial reactions between FeSO4 (aq.) and benzenehexathiol (BHT) in chloroform at room temperature and at 45 °C give bis(dithiolato)iron nanosheets 1-RT and 1-H, respectively. Nanosheets were characterized by IR, UV-Vis, SEM-EDS, TEM, XPS and PXRD. 1-H is remarkably more crystalline than 1-RT and its chemical structure resembles not the porous nickel-BHT nanosheet ([Ni3(C6S6)2]n, “Type 1”) but the non-porous copper-BHT nanosheet ([Cu3(C6S6)]n, “Type 2”), evidenced by PXRD data. Electrical conductivity of 1-H is 0.68 S cm−1 with Ea = 270 meV.

収録刊行物

• Chemistry Letters

  Chemistry Letters 50 (4), 576-579, 2020-12-15

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360006231386664320
• NII論文ID: 130008025790
• DOI: 10.1246/cl.200797
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/50/4/576/56306988/cl.200797.pdf
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