自己修復性ポリオレフィンの合成と性質

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  • 西浦 正芳
    理化学研究所開拓研究本部侯有機金属化学研究室
  • 侯 召民
    理化学研究所開拓研究本部侯有機金属化学研究室

書誌事項

タイトル別名
  • Synthesis and Properties of Self-healing Polyolefin
  • ジコ シュウフクセイ ポリオレフィン ノ ゴウセイ ト セイシツ

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<p>This article describes a new class of self-healing materials formed by the copolymerization of ethylene and anisyl-substituted propylenes using a sterically demanding half-sandwich scandium catalyst. The copolymerization proceeded in a controlled fashion, affording unique multi-block copolymers composed of relatively long alternating ethylene-alt-anisylpropylene sequences and short ethylene−ethylene units. By controlling the molecular weight and varying the anisyl substituents, a series of copolymers that show a wide range of glass-transition temperatures (Tg) and mechanical properties have been obtained. The copolymers with Tg below room temperature showed remarkable self-healability, being able to autonomously self-heal upon mechanical damage not only in a dry environment but also in water and aqueous acid and alkaline solutions, while those with Tg around or above room temperature exhibited excellent shape-memory property. The unique mechanical properties may be ascribed to the phase separation of the crystalline ethylene−ethylene nanodomains from the ethylene-alt-anisylpropylene matrix.</p>

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